Hi Paul -
When I open this newer file, I see this:
It sounds like you still have Grasshopper open and that is interfering with the display in the Rhino viewports. When you have baked geometry from Grasshopper, you are basically done with it and can just close it.
Apart from that, a few notes:
As you see in the picture above, the current display mode of that viewport is set to “Arctic”. This display mode won’t show you any materials. To preview materials, you need to set the viewport to “Rendered” or, perhaps, “Raytraced”.
It appears that you have baked the Grasshopper geometry several times and you have identical geometry overlapping itself in Rhino. This will likely cause issues when rendering.

Running SelDup
and Delete
will delete 255 objects.
Your baked objects are all on the layer called Standard
and there is no material assigned to that layer.
Having deleted duplicates and putting the viewport in the Rendered
display mode, it looks like you have assigned a few different materials to the objects.
The transparent looking objects have the “Glass” material applied:
And, as far as I can tell, the rest is set to use the layer material, which is just the default white.
There are only two materials in your file but “Metall” is not being used by any object.

After closing Grasshopper, I would delete the duplicate objects, select them all, and set the material to use the layer material:
Then use the circle in the layer panel to set the material to use the “Metall” material.

-wim