From the information page about Squish when it was introduced several years ago: Advanced Flattening [McNeel Wiki]
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Smash - is a special version of UnRollSrf that does not check to see if the surface is developable. It is not recommended now that Squish is available.
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Squish new - makes a flat pattern from a 3D non-developable (curved in two directions) surface or polygon mesh. In general, try UnRollSrf first.
Pascal commented in an earlier thread about the difference between Smash and Squish: UnrollSrf UnrollUV UnrolSrfOld Smash SmashOld (FlowAlongSrf)
In addition to the material properties which Jeff mentioned, the fabrication method used to introduce compound curvature into the metal will affect the physical “flattened” shape which corresponds to the finished item.
If metal will the metal be locally stretched by hammering or rolling on an English wheel? Or will the metal be locally shrunken? Or a combination of the two? Or will the metal be bent over a series of frames without any direct control of the deformation?